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Research Publications

  1. F. Kuttassery, Y. Ohsaki, A. Thomas, R. Kamata, Y. Ebato, H. Kumagai, R. Nakazato, A. Sebastian, S. Mathew, H. Tachibana, O. Ishitani, H. Inoue, A molecular Z-scheme artificial photosynthetic system under the bias-free condition for CO2 reduction coupled with two electron water oxidation: Photocatalytic production of CO/HCOOH and H2O2, Angew. Chemie. Int. Ed., Accepted, (2023) DOI: 10.1002/anie.202308956,  (Hot Article!)

  2. M. R. Melechalil, K. Arakawa, Y. Hirade, F. Kuttassery, T. Shimada, T. Ishida, S. Takagi. Enhanced Fluorescence behaviour of Safranine-O by complexing with inorganic clay nanosheets, Journal of Photochemistry and Photobiology, 15, 100182, (2023), (DOI: 10.1016/j.jpap.2023.100182)

  3. A. Thomas, Y. Ohsaki, R. Nakazato, F. Kuttassery, S. Mathew, S. N. Remello, H. Tachibana, H. Inoue. Molecular charactrestics of water insoluble Tin-Porphyrins for designing the one-photon-induced two-electron oxidation of water in artificial photosynthesis, Molecules, 28(4), 1882, (2023), (DOI: 10.3390/molecules28041882)

  4. S. Mathew, A. Sebastian, F. Kuttassery, Y. Yamauchi, T. Isobe, T. Hatanake, Y. Funahashi, H. Tachibana, H. Inoue. Supramolecular aluminium - based molecular catalyst for water oxidation into H2O2 in saline water, Sustainable Energy & Fuels, 6(18), 4256 - 4264, (2022) (DOI: 10.1039/D2SE00972B

  5. F. Kuttassery, H. Kumagai, R. Kamata, Y. Ebato, M. Higashi, H. Suzuki, R. Abe, O. Ishitani. Supramolecular photocatalysts fixed on the inside of the polypyrrole layer in dye sensitized molecular photocathodes: Application to photocatalytic CO2 reduction coupled with water oxidation. Chemical Science, 12(39), 13216-13232(2021), (DOI: 10.1039/D1SC03756K)

  6. S. Mathew, A. Sebastian, F. Kuttassery, S. Takagi, H. Tachibana, H. Inoue. Acid-base equilibria of axial ligands and peripheral pyridyl group with stepwise formation of nine species of aluminum(III) tera(4-pyridyl) porphyrins. Inorganica Chimica Acta, 120529 (2021) (DOI: 10.1016/j.ica.2021.120529

  7. K. Sano, F. Kuttassery, T. Shimada, T. Ishida, S. Takagi, B. Ohtani, A. Yamakata, T. Honma, H. Tachibana, H. Inoue. Optically transparant colloidal dispersion of titania nanoparticles storable for longer than one year prepared by sol/gel progressive hydrolysis/condensation. ACS Applied Materials & Interfaces, 12(40), 44743-44753 (2020) (DOI: 10.1021/acsami.0c12951)

  8. Y. Ohsaki, A. Thomas, F. Kuttassery, S. Mathew, S.N. Remello, T. Shimada, T. Ishida, S. Takagi, H. Tachibana, H. Inoue. Two-electron oxidation of water to form hydrogen peroxide initiated by one-electron oxidation of Tin (IV)-porphyrins, J. Photochem. Photobiol. A: Chem. 401, 112732 (2020). (DOI: 10.1016/j.jphotochem.2020.112732)

  9. A. Sebastian, S.N. Remello, F. Kuttassery, S. Mathew, Y. Ohsaki, H. Tachibana, H. Inoue. Protolytic behavior of water-soluble zinc (II) porphyrin and the electrocatalytic two-electron water oxidation to form hydrogen peroxide. J. Photochem. Photobiol. A: Chem. 400, 112619 (2020). (DOI: 10.1016/j.jphotochem.2020.112619)

  10. F.Kuttassery, S. Mathew, H. Tachibana, H. Inoue, How one-photon can induce water splitting into hydrogen peroxide and hydrogen by aluminum porphyrins. Rationale of the thermodynamics. Sustainable Energy & Fuels, 4(4), 1945-1953 (2020) (DOI: 10.1039/D0SE00044B)

  11. F.Kuttassery, S.Sagawa, S. Mathew, Y. Nabetani, A. Iwase, A. Kudo, H. Tachibana, H. Inoue. Water Splitting on Aluminum Porphyrin to form Hydrogen and Hydrogen Peroxide by One Photon of Visible light. ACS Applied Energy Materials, 2, 11, 8045-8051 (2019) (DOI: 10.1021/acsaem.9b01552)

  12. F. Kuttassery, A. Sebastian, S. Mathew, H. Tachibana, H. Inoue. Promotive effect of bicarbonate ion on water oxidation to form H2O2 catalyzed by aluminum porphyrins. . ChemSusChem 12, 1939-1948 (2019) (DOI: 10.1002/cssc.201900560)

  13. F. Kuttassery, S.Mathew, S.N. Remello, A.Thomas, K.Sano, Y. Ohsaki, Y. Nabetani, H. Tachibana, H. Inoue. Alternative route to bypass the bottle-neck of water oxidation: Two-electron oxidation of water catalyzed by earth-abundant metalloporphyrins, Coordination Chemistry Reviews, 377, 64-72 (2018) (DOI: 10.1016/j.ccr.2018.08.027)

  14. Y. Ohsaki, A. Thomas, F. Kuttassery, S. Mathew, S.N. Remello, Y. Nabetani, T. Shimada, S. Takagi, H.Tachibana, H.Inoue. How does the Tin(IV) insertion to porphyrins proceed in water at ambient temperature?: Re-investigation by time dependent 1H-NMR and detection of intermediates, Inorganica Chimica Acta, 482, 914-924 (2018) (DOI: 10.1016/j.ica.2018.07.036).

  15. S.N. Remello, F. Kuttassery, S.Mathew, A.Thomas, D.Yamamoto, Y.Nabetani, K.Sano, H.Tachibana, H.Inoue. Two-electron oxidation of water to form hydrogen peroxide catalysed by silicon-porphyrins. Sustainable energy & Fuels, 2, 1966-1973 (2018) (DOI: 10.1039/C8SE00102B ) (Selected as cover page of the issue)

  16. A. Thomas, F. Kuttassery, S. Mathew, S.N. Remello, Y. Ohsaki, D. Yamamoto, Y. Nabetani, H. Tachibana, H. Inoue. Protolytic behavior of axially coordinated hydroxyl groups of Tin (IV) porphyrins as promising molecular catalyst for water oxidation. J. Photochem. Photobiol. A: Chem. 358, 402-410 (2018) (DOI: 10.1016/j.jphotochem.2017.09.053)

  17. F. Kuttassery, D.Yamamoto, S. Mathew, S. N. Remello, A.Thomas, Y. Nabetani, A. Iwase, A. Kudo, H. Tachibana, H. Inoue., Photochemical hydrogen evolution on metal ion surface- grafted TiO2 particles prepared by sol/gel method without calcination J. Photochem. Photobiol. A: Chem. 358, 386-394 (2018) (DOI: 10.1016/j.jphotochem.2017.09.048)

  18. S.Mathew, F. Kuttassery, S.N. Remello, A. Thomas, D. Yamamoto, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue. Two-electron oxidation of water initiated through one-photon excitation of aluminum porphyrins: Detection of key intermediates and molecular mechanism ChemPhotoChem 2, 240-248 (2018) (DOI: 10.1002/cptc.201700155) (Highlighted as Very Important Paper)

  19. F. Kuttassery, S. Mathew, S. Sagawa, S. N. Remello, A.Thomas, D. Yamamoto, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue, One electron-initiated two-electron oxidation of water by aluminum porphyrins with earth’s most abundant metal. ChemSusChem 10, 1909-1915 (2017) (DOI: 10.1002/cssc.201700322) ( Selected as cover page of the issue)

  20. A. Thomas, F. Kuttassery, S. N. Remello, S. Mathew, D. Yamamoto, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue, Facile Synthesis of Water Soluble Cationic Tin (IV) Porphyrins and Water Insoluble Tin (IV) Porphyrins in Water at Ambient Temperature. Bull. Chem. Soc. Jpn.,89, 902-904 (2016) (DOI:10.1246/bcsj.20160091).

  21. S. Mathew, F. Kuttassery, D. Yamamoto, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue, One-Pot Facile Synthesis of Water-Soluble Cationic Aluminum(III) Porphyrins in a Unique Heterogeneous System at Ambient Temperature. Bull. Chem. Soc. Jpn. 89, 334-336 (2016)( DOI: 10.1246/bcsj.20150388).

  22. S. N. Remello, F. Kuttassery, T. Hirano, Y. Nabetani, D. Yamamoto, S. Onuki, H. Tachibana, H. Inoue, Synthesis of water-soluble silicon-porphyrin: protolytic behaviour of axially coordinated hydroxy groups. Dalton Trans. 44, 20011-20020 (2015)(DOI: 10.1039/C5DT03654B).

  23. S. N. Remello, T. Hirano, F. Kuttassery, Y. Nabetani, D. Yamamoto, S. Onuki, H. Tachibana, H. Inoue, Visible light induced oxygenation of alkenes with water sensitized by silicon-porphyrins with the second most earth-abundant element. J. Photochem. Photobiol. A: Chem. 313, 176-183 (2015)(DOI: 10.1016/j.jphotochem.2015.07.016).

  24. S. Mathew, F. Kuttassery, Y. Gomi, D. Yamamoto, R. Kiyooka, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue, Photochemical oxygenation of cyclohexene with water sensitized by aluminium (III) porphyrins with visible light. J. Photochem. Photobiol. A: Chem. 313, 137-142 (2015) (DOI: 10.1016/j.jphotochem.2015.06.001).

  25. F. Kuttassery, S. Mathew, D. Yamamoto, S. Onuki, Y. Nabetani, H. Tachibana, H. Inoue, 1. Artificial Photosynthesis Sensitized by Metal Complexes: Utilization of a Ubiquitous Element. Electrochemistry 82, 475-485 (2014) (DOI:10.5796/electrochemistry.82.475).

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